1、南京理工大學(xué)碩士學(xué)位論文酰胺類固化劑的合成工藝研究及反應(yīng)機(jī)理探索姓名：楊敬梅申請學(xué)位級別：碩士專業(yè)：有機(jī)化學(xué)指導(dǎo)教師：方志杰20080625Abstract碩士論文AbstractThecuringagentsof13hydroxyalkylamidesarewidelyusedinpolyesterswhichcontaincarboxylandanhydridegroupsbecauseoftheirnontoxicityhighe

2、fficiencyeconomyandecologyFirstlythispaperfocusedonsynthesisandtechnologyofN，N，N’，N’tetra(p—hydroxyethyl)adipamidebasedonsinglefactorexperiments，orthogonalexperimentsandchoiceofauxiliariesunderratioofstoichiometriccoeffi

3、cientTheyieldreached907％wimmeltingpointmeetingrequirementMoreovertwostepsynthesisandgradienttemperaturereducingsynthesiswerestudiedBy—productWasidentifiedby1HNMRinordertoexplorereactionmechanismSecondly，N，N—bis(13一hydrox

4、yethyl)benzoylamideWassynthesizedfirstbyaminolysisofmethylbenzoatewitlldiethanolamineusingamethodofpreparingN’N，N’，Ntetra(13一hydroxyethyl)adipamideSyntheticaltechnologyWasstudied、析tllhelpofGCandoptimalreactionconditionWa

5、sobtainedUnderthiscondition，yieldWasabout878％Liquid—liquidcontinuousextractorwhichWasdesignedinpersonWasusedtoseparatetargetproductThirdlyyellowingofNNN’，Ntetra(phydroxyethyl)adipamidelimitsitsapplicationInthispapersynth

6、esisofN，N，N’Ntetra(acryloxyethyl)adipamide(I)andN，N，N’Ntetra(epoxypropyloxyethyl)adipamide(ii)asitsderivativeswereexploredtoexpanditsnewuseMethodsof‘。acrylicacid’4，‘“methylacrylate”and‘。acryloylchloride“weretriedtOsynthe

7、sizeIResultsrevealedthatmethodofacryloylchloridehadlowreactiontemperatureanddegreeofpolymerizationwhichgavehighyieldcomparedtOmethodsofacrylicacidandmethylacrylateTwo—stepmethodundercatalystofacidandonestepmethodundercat

8、alystofbasewerestudiedtoprepareIIResultsrevealedmatnolowpolaringredientWasfoundintwostepmethodwhichWasinferiortoone—stepmethodFinallyphotocuringagentofN，NdiallyladipamideandNallylbenzoylamidewerepreparedbothwimayieldofov