1、學(xué)校代碼：—102—00分類(lèi)號(hào)：06__22⑧研究生學(xué)號(hào)：—1020020—0421082密級(jí)：五東牡拇予葒大孽碩士學(xué)位論文二烷硫基亞甲基丙二酸異核配合物的合成、結(jié)構(gòu)及性質(zhì)研究Synthesis，StructureandPerformanceoftheheteronuclearComplexeswithAlkylenedithiomethyleneMalonicAcidAsCoordinationAgent作者：凌素芹指導(dǎo)教師學(xué)科專(zhuān)業(yè)研

2、究方向?qū)W伉類(lèi)型邵允副教授有機(jī)化學(xué)有機(jī)合成學(xué)歷碩士東北師范大學(xué)學(xué)位評(píng)定委員會(huì)2007年5月AbstractAsthecalboxylcomplexeshavespecialpropertiesanddiversiformstructure，thesecomplexeshaveextensivepotentialapplicationinmanyfieldssuchasmagnetics，catalystmoleculecarriers，g

3、asstorageandergonomicsSothestudyofthecomplexesandcoordinationpolymersenrichedthestudyoftheoriesThesecompoundshavethepotentialapplicationinmanyfieldsInthisstudyaldyl【encdithiomethyleneMalonicacidactsasthemaincoordinationa

4、gentsandcompoundironionhavebeensynthesizedbytheme紐qsofsolutionAsaresult，theIDpolymerisobtainedThen3doordinationcomplexesandpolymershavebeendesignedandsynthesizedinthislDpolymerThesecompoundshavebeencharacterizedbyXraysin

5、glecrystaldiffractionanalysis，andsomepropertiesofthemhavebeenhavebeentestedandanalyzed1IncoordinationcompoundNa[Fe(HDYM)2(DYM)]’10H20(IIDYM=2一(1，3dithiolan2ylidene)malonicacidThelocalenvironmentofironexhibitsdistortedoct

6、ahedroncoordinatedwithtwocarboxylatooxyenatomsfzonHdymaEachdymwithF“II)ionparticipatesinformingsixmemberedchealthingrin黟。ThereexistsbondinteractiongsamongllallillHlandOxygenatomstiomcoordinatewatermoleculeandBncoordinate

7、dealboxylategroups，exhibitsanamorphieoctahedrom2TransitionmetaldinuclealcomplexesC03Fe2(dyma)6(H20)14]’7H20(Hdyma2【l，3】dithiolan2ylidenernalonicacimThelocalmetalionofeachadoptsasixcoordinatedexhibitsdistortedoctahedromFe

8、(2)coordinationtotwofiveoxyenatomsoftwocheatingealboxylategroupsoftwoHdymaligandscreatedasixmemberedehealthingringsCoO)ionandCo(2)ion麗thadymaadoptsficarboxylobandcompoundedthencompoundwithfiveOxygenatomsfromcoordinatewat

9、erCo(3)ionwiththeothertwohymacompoundbydearboxylobondthencompoundwithfiveOxygenatomsfromcoordinatewater3f[NaFe2Mn2(HdymaXdyma)5(H20)10]‘6H20nislieal(1D)coordinationpolymerbytheconnectionofO(12)ThearrangenentofManganeseio

10、nisW：FermmionandmanganeseioncoordinatedwithdymabyseveradaprochesSuchas15bidentatechealth13bidentatcchealthandandsoonTheionsoffeandManganeseionandFcrmmionalehexdcoordnatedThelOCalenvironmentofironexhibitsdistortedoctahedr

11、om4ThelocalmetalionsFc(11andFe(2)ofthecalboxylcomplesx[Z_212Fe2(Hdyma)2(dyllla)4(I120)2]lOH20nalesixcoorinatall，andexhibitsdistortedoctahedronThlocalZincionsZn(1)andZn(2)alefourcoorinatell，eachZincionslinkedwithI_teorbox